I've downloaded the county boundaries (1 million scale) from this link: http://nationalmap.gov/small_scale/atlasftp.html?openChapters=chpbound#chpbound
A sample of the attributes in the dataset is:
ADMIN_NAME, ADMIN_FIPS, STATE, STATE_FIPS, NAME, SUFFIX, POP, SQ_MILES, PRIM_MILES, COUNTYP010...